IndiumV3, Main, Repository, bibRecord, 001F11

Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells

Identifieur interne : 001F11 ( Main/Repository ); précédent : 001F10; suivant : 001F12

Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells

Auteurs : RBID : Pascal:12-0403773

Descripteurs français

Pascal (Inist)
- Argent, Nanoparticule, Nanomatériau, Sulfure de cuivre, Sulfure d'indium, Polymère, Cellule solaire, Matériau électrode, Travail sortie, Niveau énergie, Couche intermédiaire, Couche interfaciale, Dérivé du thiadiazole, Nanocomposite, Facteur remplissage, Structure cristalline, Microscopie électronique transmission, Spectrométrie masse temps vol, Couche oxyde, Substrat aluminium, Al2O3, 8107W, 8460J, 8245F.
Wicri :
- concept : Argent, Polymère.

English descriptors

KwdEn :
- Copper sulfide, Crystal structure, Electrode material, Energy levels, Fill factor, Indium sulfide, Interfacial layer, Interlayers, Nanocomposites, Nanoparticles, Nanostructured materials, Oxide layer, Polymers, Silver, Solar cells, Thiadiazole derivatives, Time of flight mass spectroscopy, Transmission electron microscopy, Work functions.

Abstract

Electrode materials are primarily chosen based on their work function to suit the energy levels of the absorber materials. In this paper, we focus on the modification of aluminum cathodes with a thin silver interlayer (2 nm) in copper indium sulfide/poly[(2,7-silafluorene)-alt-(4,7-di-2-thienyl-2,1,3-benzothiadiazole)] (PSiF-DBT) nanocomposite solar cells, which improves the fill factor compared to pure aluminum electrodes. A comprehensive structural investigation was performed by means of transmission electron microscopy and time-of-flight secondary ion mass spectrometry revealing the presence of silver nanoparticles in an aluminum oxide matrix between the absorber layer and the aluminum cathode. In combination with complementary optical investigations, the origin of the improvement is ascribed to a facilitated charge extraction.

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Pascal:12-0403773

Le document en format XML

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<author><name sortKey="Pein, Andreas" uniqKey="Pein A">Andreas Pein</name>
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<author><name sortKey="Haas, Wernfried" uniqKey="Haas W">Wernfried Haas</name>
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<author><name sortKey="Hofer, Ferdinand" uniqKey="Hofer F">Ferdinand Hofer</name>
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<author><name sortKey="Krebs, Frederik C" uniqKey="Krebs F">Frederik C. Krebs</name>
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<author><name sortKey="Rat, Thomas" uniqKey="Rat T">Thomas Rat</name>
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<author><name sortKey="Trimmel, Gregor" uniqKey="Trimmel G">Gregor Trimmel</name>
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<date when="2012">2012</date>
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<seriesStmt><idno type="ISSN">1932-7447</idno>
<title level="j" type="abbreviated">J. phys. chem., C</title>
<title level="j" type="main">Journal of physical chemistry. C</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Copper sulfide</term>
<term>Crystal structure</term>
<term>Electrode material</term>
<term>Energy levels</term>
<term>Fill factor</term>
<term>Indium sulfide</term>
<term>Interfacial layer</term>
<term>Interlayers</term>
<term>Nanocomposites</term>
<term>Nanoparticles</term>
<term>Nanostructured materials</term>
<term>Oxide layer</term>
<term>Polymers</term>
<term>Silver</term>
<term>Solar cells</term>
<term>Thiadiazole derivatives</term>
<term>Time of flight mass spectroscopy</term>
<term>Transmission electron microscopy</term>
<term>Work functions</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Argent</term>
<term>Nanoparticule</term>
<term>Nanomatériau</term>
<term>Sulfure de cuivre</term>
<term>Sulfure d'indium</term>
<term>Polymère</term>
<term>Cellule solaire</term>
<term>Matériau électrode</term>
<term>Travail sortie</term>
<term>Niveau énergie</term>
<term>Couche intermédiaire</term>
<term>Couche interfaciale</term>
<term>Dérivé du thiadiazole</term>
<term>Nanocomposite</term>
<term>Facteur remplissage</term>
<term>Structure cristalline</term>
<term>Microscopie électronique transmission</term>
<term>Spectrométrie masse temps vol</term>
<term>Couche oxyde</term>
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<term>8460J</term>
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<front><div type="abstract" xml:lang="en">Electrode materials are primarily chosen based on their work function to suit the energy levels of the absorber materials. In this paper, we focus on the modification of aluminum cathodes with a thin silver interlayer (2 nm) in copper indium sulfide/poly[(2,7-silafluorene)-alt-(4,7-di-2-thienyl-2,1,3-benzothiadiazole)] (PSiF-DBT) nanocomposite solar cells, which improves the fill factor compared to pure aluminum electrodes. A comprehensive structural investigation was performed by means of transmission electron microscopy and time-of-flight secondary ion mass spectrometry revealing the presence of silver nanoparticles in an aluminum oxide matrix between the absorber layer and the aluminum cathode. In combination with complementary optical investigations, the origin of the improvement is ascribed to a facilitated charge extraction.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells</s1>
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<s5>12</s5>
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<s5>33</s5>
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   |clé=     Pascal:12-0403773
   |texte=   Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells
}}

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Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells

Comprehensive Investigation of Silver Nanoparticle/Aluminum Electrodes for Copper Indium Sulfide/Polymer Hybrid Solar Cells

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